5-Cyclohexyl-2-methyl-3-(3-methylphenylsulfonyl)-1-benzofuran
نویسندگان
چکیده
In the title compound, C22H24O3S, the cyclo-hexyl ring adopts a chair conformation. The dihedral angle between the mean plane [r.m.s. deviation = 0.010 (1) Å] of the benzo-furan ring system and the benzene ring is 81.78 (4)°. In the crystal, mol-ecules are linked via pairs of C-H⋯π inter-actions into inversion dimers. These dimers are further linked by C-H⋯π inter-actions into supra-molecular chains running along the b-axis direction. In addition, C-H⋯O hydrogen bonds are observed between inversion-related dimers.
منابع مشابه
5-Cyclohexyl-2-methyl-3-(3-methylphenylsulfinyl)-1-benzofuran
In the title compound, C22H24O2S, the cyclo-hexyl ring adopts a chair conformation. The dihedral angle between the mean planes of the benzo-furan and 3-methyl-phenyl moieties is 86.48 (4)°. In the crystal, mol-ecules are connected along the a-axis direction by two different inversion-generated pairs of C-H⋯π and C-H⋯O inter-actions.
متن کامل5-Cyclopentyl-2-methyl-3-(4-methylphenylsulfonyl)-1-benzofuran
In the title compound, C21H22O3S, the cyclo-pentyl ring adopts a twist conformation. The dihedral angle between the mean planes of the benzo-furan and 4-methyl-phenyl rings is 72.38 (6)°. In the crystal, mol-ecules are linked by C-H⋯O and C-H⋯π inter-actions, forming a three-dimensional supra-molecular network.
متن کامل5-Cyclohexyl-2-methyl-3-(4-methylphenylsulfonyl)-1-benzofuran
In the title compound, C(22)H(24)O(3)S, the cyclo-hexyl ring adopts a chair conformation. The 4-methyl-phenyl ring makes a dihedral angle of 80.95 (4)° with the mean plane [mean deviation = 0.011 (1) Å] of the benzofuran fragment. In the crystal, mol-ecules are linked by weak C-H⋯O and C-H⋯π inter-actions.
متن کامل5-Chloro-2-methyl-3-(4-methylphenylsulfonyl)-1-benzofuran
The title compound, C16H13ClO3S, crystallized with two independent mol-ecules in the asymmetric unit. The 4-methyl-phenyl rings make dihedral angles of 75.15 (4)° and 72.18 (4)° with the planes of the benzo-furan ring systems in the two mol-ecules. In the crystal, mol-ecules are linked by weak C-H⋯O and C-H⋯π inter-actions, forming a three-dimensional network.
متن کامل5-Chloro-2,7-dimethyl-3-(3-methylphenylsulfonyl)-1-benzofuran
In the title compound, C17H15ClO3S, the dihedral angle between the mean planes of the benzo-furan and 3-methyl-phenyl rings is 76.99 (4)°. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds into chains along the b-axis direction. These chains are linked by π-π inter-actions between the benzene and furan rings of neighbouring mol-ecules [centroid-centroid distance = 3.976 (2) Å].
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عنوان ژورنال:
دوره 70 شماره
صفحات -
تاریخ انتشار 2014